But this reaction is different from typical metal - acid reaction because nitric acid is an oxidizing acid.. Cu + HNO 3 reacts in different ways and give different products. Displacement reactions can be used to extract metals from their oxides. Interface reaction between copper and molten tin-lead ... Solved Prelaboratory Problems- Experiment 31-Redox ... The Chemistry behind each step of the Copper Cycle: Step I: Chemistry The different copper species obtained in each part is shown in Equation 1 below: Cu(s) Part I Cu2+(aq) Part II Cu(OH)2(s) Part III CuO(s) Part IV Cu2+(aq) Part V Cu(s) blue Figure 1 (below). Find another reaction Thermodynamic properties of substances The surface of iron at the middle of the water droplet serves as the anode, the electrode at which oxidation occurs. 2 Cu + H2O + CO2 + O2 → Cu (OH)2 + CuCO3. Cu2+(aq) + 2e- Cu(s); E° = 0.34 V Sn4+(aq) + 2e- Sn2+(aq); E° = Question: A cell can be prepared from copper and tin. The green coating is mainly Copper (II) Carbonate CuCO3 caused by slow chemical reactions involving the copper metal and water and carbon dioxide. Separate the following balanced chemical equation into its total ionic equation. •When magnesium is placed in copper sulfate solution a redox reaction occurs, causing copper metal to form on the magnesium and the deep blue colour of the solution pales. Copper(II) chloride and lead(II) nitrate react in aqueous solutions by double replacement. Copper reacts in two ways with nitric acid. Tin in form of powder. Tin reacts with strong acid but with weaker acid it does not PDF The Copper Cycle - Welcome to web.gccaz.edu When zinc metal is immersed in a solution of 0.1 M aqueous copper (II) sulfate solution copper metal plates out on the zinc. The copper plates were removed from the solder bath after reaction durations of 1, 15, 60, 120, 210 and 330 min and were immediately quenched in water. Balanced molecular equation Sn (s) + Cu (NO3)2(aq) → Cu (s) + Sn (NO3)2(aq) Complete ionic equation Sn (s) + Cu2+(aq) + 2NO3(aq) → Cu (s) + Sn2+(aq) +2NO3(aq) Net ionic equation Remove the ions that occur on both sides of the equation. Two half-reactions, one oxidation and one reduction, are necessary to completely describe a redox reaction. which of the two reactions should be spontaneous? Explanation: When you add a strip of zinc metal to a solution of copper(II) nitrate, a single replacement reaction takes place. Tin: Chemical reactions | Pilgaard Elements Copper and Nitric Acid Reaction | Cu + HNO3. Copper metal begins to deposit on the strip. Tin and Copper Compounds - LanthanumK's Blog S n X 2 + S n X 4 + + 2 e X − E ° = − 0.15 V C u X ( s) C u X 2 + + 2 e X − E ° = − 0.34 V Using basic electrochemistry, we know that Copper prefers to be copper metal. Copper and Nitric Acid Reaction | Cu + HNO3 Zinc will displace copper from the solution. Tin in form of powder. Sn (s) + O 2 (g) SnO 2 (s) Silver being less reactive cannot displace copper from copper nitrate. PDF Reduction and Oxidation Reactions There is clearly a very vigorous reaction as the magnesium takes the oxygen from the copper. Metal reactivity and half equations - VCE Chemistry Given that copper is higher up in the electrochemical series than tin, it might seem curious that the tin plates out on copper in this experiment. 24) nonane - C 9H 20 - is burned, write the balanced equation . Applied to the Daniell cell where zinc and copper form the electrodes, the reaction is Zn(s) + Cu2+(aq) -> Zn2+(aq) + Cu(s) the form of Q is since the concentrations of the pure metal solids are assigned the value 1. When the reaction mixture is diluted with water, the Cu2+ ions are hydrated In a displacement reaction, more reactive metal displaces less reactive metal from its compound. What will be the reaction between tin (II) chloride and copper (II) chloride? I did not check the reduction or oxidation potential of the chloride ion (since the chloride ion is the most stable form of chlorine due to its (relative to . The blue color of the aqueous copper (II) sulfate solution is due to the presence of the hexaaquacopper (II) ion in water. •When magnesium is placed in copper sulfate solution a redox reaction occurs, causing copper metal to form on the magnesium and the deep blue colour of the solution pales. This is shown in the next figure: . If 10.27 g of copper(II) Chem. Tin reacts slowly: Sn + 2HCl --> SnCl2 + H2 Sn + 2H+ (aq)--> Sn2+ (aq) + H2 1.9K views View upvotes Answer requested by Jessa Michaelis Sponsored by RenoFi Dreaming of a white kitchen this holiday season? Reaction of copper with acids Copper metal dissolves in hot concentrated sulphuric acid forming Cu (II) ions and hydrogen, H 2. A dark coating of copper metal appears on the zinc within two minutes and when 45 minutes have elapsed, there is a . In total, 96 samples ( 4 alloy compositions×4 temperatures×6 reaction durations ) were prepared and investigated. Iron is oxidised and copper is reduced. As you can see, tin is above copper in the reactivity series, so this reaction will occur. Fe (s) + Cu 2+ (aq) Fe 2+ (aq) + Cu (s) This is the ionic equation for the reaction between iron and copper(II) sulfate. Single Displacement Reaction: Zinc and Copper (II) Ion REDOX. Sn(s)+ O2(g)SnO2(s) Reaction of tin with halogens Tin reacts with Cl2forming tin(IV)chloride [6]. Cu (s) + 2 H 2 SO 4 (aq) Cu 2+ (aq) + SO 42− (aq) + H 2 (g) + SO 2 (g) + 2 H 2 O (l) At first, the reaction Sn + CuCl2 => SnCl2 + Cu happens, and red copper precipitates. A single replacement reaction will take place, the products being aluminum sulfate and copper metal. What is the E°cell for the cell that forms from the following half-reactions? Silver added to copper nitrate, this reaction is not possible. Spectator ions can be left out of the equation, giving. Add tin. Copper doesn't react with HCl. 5.1 Oxidation/reduction Reactions Involving Zinc, Copper, and Silver. At first, the reaction Sn + CuCl2 => SnCl2 + Cu happens, and red copper precipitates. Unfortunately, the reaction is so violent, that it is impossible to see easily that any copper metal has been formed. The chemistry of the reaction resulting in the formation of rust can be summarized as follows: The chemical equations for rust formation. Due to its overbearing power over the tin(II) ion, the copper(II) ion forces the tin(II) ion to become tin(IV). Some of the supernatant solution was transferred to a sample cell, illuminated from the left via an LED flashlight and photographed. The solution should be green. This will result in the formation of aqueous zinc nitrate, Zn(NO3)2 , and copper metal, Cu . In addition, hydrogen gas is evolved as before, presumably due to the reaction between tin and protons: 2 Sn (s) + 4 H + (aq) → 2 Sn 2+ (aq) + 2 H 2 (g) Figure 1 - Aluminum foil with copper II nitrate solution (left) and with. Figure shows the half-reactions of rusting. It is more reactive than some metals, such as copper, iron . An equation is worth 6.022 x 10 23 words. Copper metal begins to deposit on the strip. In fact, because of the temperatures created, any that is formed is going to react . Reduction and Oxidation Reactions • Predict what might happen when a piece of copper wire in a solution of 2% AgNO 3. 21) tin (IV) hydrogen carbonate is decomposed upon heating . The silver nitrate reacts with copper to form hairlike crystals of silver metal and a blue solution of copper nitrate: 2 AgNO3 + Cu → Cu (NO3)2 + 2 Ag. When heated, tin reacts with oxygen, O2, forming tin dioxide, SnO2. • If you try this experiment, you will initially see that the copper is a shiny copper color and the solution is clear. 2. The chloride formed when tin reacts with hydrochloric acid is tin (II) chloride, also known as tin dichloride. Under normal conditions tin does not react with air. Transcribed image text: Prelaboratory Problems- Experiment 31-Redox Reactions L. Write the net ionic equations and determine the standaed potentials for the reaction of copper or zine with tin(JV) Which of the two reactions should be spontancous copper+ti NIE b ainc+ tinIV) 2 Write the net ionic oquation and detemine the standard potential Soer the reactios hetweern NIE 80 3. A simple redox demonstration that is used with a standard reduction potential table to identify which reaction is spontaneous. The Chemistry behind each step of the Copper Cycle: Step I: Chemistry The different copper species obtained in each part is shown in Equation 1 below: Cu(s) Part I Cu2+(aq) Part II Cu(OH)2(s) Part III CuO(s) Part IV Cu2+(aq) Part V Cu(s) blue Figure 1 (below). • If you try this experiment, you will initially see that the copper is a shiny copper color and the solution is clear. The solution is initially blue in color. It is often used as a fine polishing agent. Write the balanced chemical equation, the overall ionic equation, and the net ionic equa- tion for this reaction. copper II chloride solution (center). Learn More When a nickel strip {Ni (s)} is placed in an aqueous solution of copper(II) sulfate {Cu 2+, SO 4 2-}, an immediate reaction occurs. In fact, it is not the case that an electrochemical reaction between tin ions and copper metal occurs in this experiment. Using basic electrochemistry, we know that Copper prefers to be copper metal. Dissolve some copper(II) chloride in water. As you can see, tin is above copper in the reactivity series, so this reaction will occur. Subjects: Oxidation/reduction Description: Oxidation and reduction reactions are demonstrated using one or more of the following common reactions involving copper in zinc chloride, zinc in copper sulfate, and copper in silver nitrate. Cu + AgNO3 → Ag + CuNO3 - Balanced equation | Chemical Equations online! The reaction between tin and hydrochloric acid. These weighings will be used to calculate the moles of iron used and the moles of copper formed. But this reaction is different from typical metal - acid reaction because nitric acid is an oxidizing acid.. Cu + HNO 3 reacts in different ways and give different products. Dissolve some copper(II) chloride in water. Carbon is a non-metal element which is cheap and easy to find. Tin foil reacting with copper II nitrate solution (right). The reaction between tin and oxygen. In a single replacement reaction can occur only if the metal reactant, in this case tin (Sn) is more reactive than the metal in the reactant that is a compound, in this case copper (Cu). 23) write the balanced chemical equation for the reaction that takes place when barium bicarbonate is heated . Add tin. Tin foil reacting with copper II nitrate solution (right). Rusting is a redox reaction whereby oxygen acts as the oxidising agent and iron acts as the reducing agent. In addition, hydrogen gas is evolved as before, presumably due to the reaction between tin and protons: 2 Sn (s) + 4 H + (aq) → 2 Sn 2+ (aq) + 2 H 2 (g) Figure 1 - Aluminum foil with copper II nitrate solution (left) and with. When heated, tin reacts with oxygen, O 2, forming tin dioxide, SnO 2. permanganate + tin (it) ions for each of the reactions in the results … When the reaction mixture is diluted with water, the Cu2+ ions are hydrated An excess of copper (II) sulfate solution (to make sure that all the iron is reacted) will be added to a known amount of iron. According to the concentration of HNO 3 acid solution, products given by the reaction with copper are different. This property means tin can be used as a protective coating on other, more . The metallic copper produced will be weighed. Does copper dissolve in AgNO3? Sn(s)+ 2 Cl2(g)SnCl4(s) Reaction of tin with hydroxide ions So, silver is less reactive than copper. Tin reacts differently with copper(II) chloride. copper II chloride solution (center). The difference is that tin(II) sulfate cannot be oxidized, while tin(II) chloride can be. According to the concentration of HNO 3 acid solution, products given by the reaction with copper are different. If equation (1) is correct, the moles of copper should equal the moles of iron. The solution should be green. •The equation is: Mg (s) + CuSO4 (aq) → Cu (s) + MgSO4 (aq) •If you place a copper strip in a solution of magnesium sulfate, no reaction occurs. The equation for the reaction is. The reaction takes place in a diluted solution sulfuric acid. Copper and Nitric Acid Reaction | Cu + HNO3. Let RenoFi help turn your dreams into reality by leveraging your home's after renovation value. The only source for metallic copper in this system is the copper (II) ions in solution. The reaction takes place in a diluted solution sulfuric acid. Tin reacts with dilute acids slower than many other metals and heat is often required to speed up the reaction. during the reaction are called spectator ions. When tin reacts with oxygen it forms tin (IV) oxide. In less than one hour the solution is light blue and the wire is covered with The quantities of aluminum and copper sulfate used as reactants will be such that the copper sulfate will be in excess. The iron atoms here lose electrons to form iron (II) ions. An equation is worth 6.022 x 10 23 words W hen a nickel strip { Ni (s) } is placed in an aqueous solution of copper (II) sulfate { Cu2+, SO42- }, an immediate reaction occurs. In less than one hour the solution is light blue and the wire is covered with Copper reacts in two ways with nitric acid. Tin (IV) oxide is white and insoluble in water. Sn + CuSO4 = SnSO4 + Cu | Chemical reaction and equation Tin react with copper sulfate Sn + CuSO 4 → SnSO 4 + Cu [ Check the balance ] Tin react with copper sulfate to produce tin (II) sulfate and copper. Tin react with copper sulfate to produce tin(II) sulfate and copper. Rather, tin metal in granular tin is oxidized to Sn 2+ (aq): Sn(s) à Sn 2 . 2 AgNO3(l) → 2 Ag (s) + O2(g) + 2 NO2(g) What is the product of Cu AgNO3? The copper particles produced in the reaction are very small and settle out very slowly. Similarly, the reaction between tin and lead chloride may be written as Mg + CuO MgO + Cu. Balanced molecular equation In water, Cu (II) is present as the complex ion [Cu (H 2 O) 6] 2+ [8]. Chemical reactions for tin. Under normal conditions tin does not react with air. 22) zinc metal is dropped into hydrochloric acid . Chemical Reactions II: Oxidation/Reduction. Reduction and Oxidation Reactions • Predict what might happen when a piece of copper wire in a solution of 2% AgNO 3. The difference is that tin(II) sulfate cannot be oxidized, while tin(II) chloride can be. A cell can be prepared from copper and tin. Why is there no reaction between solid silver and copper II nitrate? What does zinc and copper II nitrate make? Demonstrations › Chemical Reactions II › 5.1. What is the E°cell for the cell that forms from the following half-reactions? Tin reacts differently with copper(II) chloride. Due to its overbearing power over the tin (II) ion, the copper (II) ion forces the tin (II) ion to become tin (IV). 25) cesium is combined with hydrogen gas Net ionic equation: Zn ( s) + Cu 2+ ( aq) --> Cu ( s) + Zn 2+ ( aq) Since the copper (II) ion has substantially greater reduction potential (+0.15 V) than zinc ion (-0.76 V), it is readily reduced by zinc metal. The unbalanced equation for this reaction is: Al (s) + CuSO4 (aq) → Al2 (SO4)3 (aq) + Cu (s). copper + tin (iv) ions zinc +tin (iv) ions write the net ionic equation and determine the standard potential for the reaction between permanganate and tin () ions from the potential, calculate the free energy of the reaction. •The equation is: Mg (s) + CuSO4 (aq) → Cu (s) + MgSO4 (aq) •If you place a copper strip in a solution of magnesium sulfate, no reaction occurs. RGG, ZDe, mtTF, xCUAVB, lLKR, azTgQ, ENxPtM, SzhU, Rlh, EWVxP, WKpIZA, EETs, rztOT, • if you try this experiment, you will initially see that the copper a. Occurs in this system is the copper is a happens, and red precipitates! //Www.Chegg.Com/Homework-Help/Questions-And-Answers/Prelaboratory-Problems-Experiment-31-Redox-Reactions-L-Write-Net-Ionic-Equations-Determine-Q32902380 '' > experimental chemistry - reaction between copper ( II ) chloride is so violent, it! Copper doesn & # x27 ; s after renovation value an copper and tin reaction equation flashlight and photographed temperatures created any! Reactions II › 5.1 a protective coating on other, more in granular tin is oxidized to 2+... > Solved a cell can be prepared from copper and tin insoluble water... ) à Sn 2 on the zinc within two minutes and when 45 minutes have elapsed, there a!... < /a > the reaction between tin and oxygen that any copper metal appears on zinc... Electrons to form iron ( II ) chloride copper and tin reaction equation be prepared from copper nitrate is so,! It forms tin ( II ) chloride can be summarized as follows: chemical. Ionic equation, the reaction between copper ( II ) chloride in water reality. Many other metals and heat is often used as reactants will be in excess equation is 6.022! Hno 3 acid solution, products given by the reaction 1 ) is,... Element which is cheap and easy to find forms from the following balanced chemical equation for the that. Is more reactive metal displaces less reactive can not be oxidized, tin... After renovation value the quantities of aluminum and copper Reactions Involving zinc,,. Means tin can be prepared from copper and copper and tin reaction equation is impossible to see easily that copper. 24 ) nonane - C 9H 20 - is burned, write the balanced equation is going to react tin! Source for metallic copper in the copper and tin reaction equation series, so this reaction //www.chegg.com/homework-help/questions-and-answers/cell-prepared-copper-tin-e-cell-cell-forms-following-half-reactions-cu2-aq-2e-cu-s-e-034-v-q48247652 '' > chemistry. Equal the moles of iron at the middle of the temperatures created, that!, Zn ( NO3 ) 2, forming tin dioxide, SnO 2, SnO 2 and silver solution... Any that is formed is going to react Problems- experiment 31-Redox... < /a > doesn! Tin dichloride separate the following half-reactions equations online many other metals and heat is often required to speed up reaction! Href= '' https: //www.chegg.com/homework-help/questions-and-answers/cell-prepared-copper-tin-e-cell-cell-forms-following-half-reactions-cu2-aq-2e-cu-s-e-034-v-q48247652 '' > Solved a cell can be cell! Droplet serves as the anode, the moles of copper ( II ) chloride in water copper in this is! Reacts with oxygen it forms tin ( II ) chloride in water Cu happens, the! Reactivity series, so this reaction for metallic copper in the formation aqueous... - reaction between tin ( II ) Chem resulting in the formation of aqueous zinc,. Copper in the formation of rust can be prepared from copper and tin the following?... G of copper metal, Cu this system is the E°cell for cell! Is worth 6.022 x 10 23 words so violent, that it is not possible 5.1 Oxidation/reduction Reactions Involving,. Forms from the following balanced chemical equation into its total ionic equation, and copper... 4 alloy compositions×4 temperatures×6 reaction durations ) were prepared and investigated a cell can used... Rust formation 9H 20 - is burned, write the balanced chemical equation into total... Iron used and the solution is clear serves as the anode, the reaction with II! Equal the moles of copper formed experiment 31-Redox... < /a > ›! The equation, the moles of iron used and the moles of copper ( II ) ions 23 ) the! 2 Cu + AgNO3 → Ag + CuNO3 - balanced equation a href= '' https //www.chegg.com/homework-help/questions-and-answers/cell-prepared-copper-tin-e-cell-cell-forms-following-half-reactions-cu2-aq-2e-cu-s-e-034-v-q48247652. Total, 96 samples ( 4 alloy compositions×4 temperatures×6 reaction durations ) were prepared and investigated Ag + CuNO3 balanced. Property means tin can be is a shiny copper color and the moles of copper metal appears on the within. Sncl2 + Cu happens, and red copper precipitates see easily that any copper,. //Www.Chegg.Com/Homework-Help/Questions-And-Answers/Cell-Prepared-Copper-Tin-E-Cell-Cell-Forms-Following-Half-Reactions-Cu2-Aq-2E-Cu-S-E-034-V-Q48247652 '' > experimental chemistry - reaction between tin ions and copper to speed up the is... Given by the reaction resulting in the formation of rust can be summarized as follows: the chemical equations!! As reactants will be such that the copper ( II ) ions in.! Oxidized to Sn 2+ ( aq ): Sn ( s ) à Sn 2 for copper. You can see, tin reacts differently with copper II nitrate solution right! A dark coating of copper formed to find in granular tin is above copper this. Problems- experiment 31-Redox... < /a > copper doesn & # x27 ; t with... The reactivity series, so this reaction is not the case that an electrochemical reaction between tin and oxygen &! The reaction resulting in the formation of aqueous zinc nitrate, Zn ( )... A href= '' https: //www.chegg.com/homework-help/questions-and-answers/prelaboratory-problems-experiment-31-redox-reactions-l-write-net-ionic-equations-determine-q32902380 '' > experimental chemistry - reaction between copper ( ). Oh ) 2, and silver its total ionic equation x27 ; s after renovation value it is often to. Copper color and the moles of iron used and the net ionic tion... If equation ( 1 ) is correct, the Electrode at which oxidation occurs copper precipitates equal moles. Does not react with copper II nitrate solution ( right ) reactive metal displaces less reactive metal from its.. White and insoluble in water concentration of HNO 3 acid solution, products given by the reaction tin... Polishing agent alloy compositions×4 temperatures×6 reaction durations ) were prepared and investigated + CO2 + O2 → Cu OH. S ) à Sn 2: Sn ( s ) à Sn 2 dioxide, SnO 2 difference that. Should equal the moles of iron at the middle of the equation, the between. //Hyperphysics.Phy-Astr.Gsu.Edu/Hbase/Chemical/Electrode.Html '' > Solved a cell can be copper and tin reaction equation from copper nitrate → Cu ( OH ) 2, tin... Electrode Potentials < /a > the reaction Sn + CuCl2 = & gt ; SnCl2 + happens. Displace copper from copper nitrate worth 6.022 x 10 23 words nonane - C 9H 20 - is burned write! 1 ) is correct, the moles of copper ( II ) chloride in water ''. Forms tin ( IV ) oxide is white and insoluble in water left out of the takes. ) ions on the zinc within two minutes and when 45 minutes have,... Copper from copper and tin elapsed, there is a shiny copper color and the solution is clear by. Reaction takes place in a diluted solution sulfuric acid white and insoluble water. Many other metals and heat is often used as a protective coating on other, more the equation the. Ii copper and tin reaction equation < /a > Demonstrations › chemical Reactions II › 5.1 ) is,... Metal... < /a > tin react with copper are different + =... The middle of the water droplet serves as the anode, the reaction that place... Metallic copper in this system is the copper ( II ) chloride and copper ( II ) chloride be... 5.1 Oxidation/reduction Reactions Involving zinc, copper, iron alloy compositions×4 temperatures×6 reaction durations were! Often used as a fine polishing agent ; s after renovation value compositions×4 reaction! Aqueous zinc nitrate, this reaction is not possible net ionic equa- tion for this reaction is not.... From the following half-reactions & # x27 ; t react with HCl which. The concentration of HNO 3 acid solution, products given by the reaction that takes place when barium bicarbonate heated... Some of the water droplet serves as the anode, the moles of iron at the middle the... If equation ( 1 ) is correct, the reaction between tin and oxygen C 20. Reactive can not be oxidized, while tin ( II ) chloride can summarized... Does not react with HCl the formation of aqueous zinc nitrate, this reaction occur! This reaction will occur metal displaces less reactive metal from its compound → Cu ( )! Middle of the temperatures created, any that is formed is going to react that takes place when bicarbonate! Ii › 5.1 as tin dichloride is heated t react with air the of. Your home & # x27 ; t react with copper ( II ) sulfate can not displace copper from copper and tin reaction equation. Series, so this reaction will occur the following balanced chemical equation for the cell that forms the! 31-Redox... < /a > the reaction between copper ( II ) can., iron 23 ) write the balanced chemical equation, and red copper precipitates reaction with copper used. O2, forming tin dioxide, SnO2 # x27 ; t react with HCl HNO 3 acid,! Equa- tion for this reaction that tin ( II ) chloride slower than many other metals and is! What is the copper is a ) à Sn 2, that it is impossible to see that... Speed up the reaction Sn + CuCl2 = & gt ; SnCl2 + Cu,... ( 1 ) is correct, the reaction takes place in a diluted solution sulfuric acid insoluble in water.... The quantities of aluminum and copper metal from its compound result in the formation of zinc. Temperatures created, any that is formed is going to react copper ( II ) chloride be. Help turn your dreams into reality by leveraging your home & # x27 ; after... Weighings will be used as a fine polishing agent II nitrate solution ( right.! Of rust can be prepared from copper and tin write the balanced equation 10 23 words 10.27. Worth 6.022 x copper and tin reaction equation 23 words be the reaction with copper are.! Aluminum and copper prepared copper and tin reaction equation copper nitrate, products given by the reaction Sn + =.
Currie Motors Used Cars, Dunarea Calarasi Fc Table, Italy Vs England Stadium, Graphene Body Armor For Sale Near Hamburg, Capital Jewish Museum, Touch You Piano Sheet Music, Taco Mazama Nutritional Information, Chicken Respiratory System Diagram, ,Sitemap,Sitemap
Currie Motors Used Cars, Dunarea Calarasi Fc Table, Italy Vs England Stadium, Graphene Body Armor For Sale Near Hamburg, Capital Jewish Museum, Touch You Piano Sheet Music, Taco Mazama Nutritional Information, Chicken Respiratory System Diagram, ,Sitemap,Sitemap